The outer layer of fabric does get hotter because the black color absorbs more heat. And that heat doesn’t get transmitted to the skin because of the thick fabric. But thin black clothing transmits that heat to the skin, making a person hotter.
Do black clothes keep you cool?
Black does absorb heat from the sun at a faster pace than white, but black also absorbs the heat from your body as well. Throw a little wind into the mix and black is the better choice for wicking away the heat away from your core.
Is it better to wear black or white in the heat?
In most cases white clothes look just like black clothes in the infrared spectrum. They both reflect about the same amount of thermal radiation. That means you are going to be better off with white clothes, since they don’t absorb as much visible light.